You need to know the risks of using biocides or other chemicals to clean your air ducts. Some chemicals can harm you and your family. Although biocides can be used to kill bacteria and mold, they should not be used in any other circumstances.
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Yes, the majority of air purifiers available on the market can remove large particles from the air. Mechanical filtration is an option that captures pollutants from filters.
There isn't any evidence to suggest that your air would be cleaner if your ducts were professionally cleaned. The EPA conducted a study on the effectiveness of air duct cleaning. The conclusion: "Duct cleaning is not proven to prevent any health issues."