Premiere:  Friday, Oct. 21 on NBC

It was the best of times, it was the worst of times, as just when Chuck's story headed in a bold new direction NBC decided to chuck Chuck to Friday nights for a final 13 episodes. Still, with their imminent end in sight, expect the writers to satisfactorily wrap up the show's mythology as we embark on the final chapter of Chuck, Sarah and Casey launching their own spy agency with Morgan as the new Intersect.

Considering it's Chuck, need we even mention the guest stars? Yes. Yes we do. Look for Luke Skywalker himself Mark Hamill in season premiere "Chuck Vs. the Zoom," and The Matrix's Carrie Anne Moss as a recurring nemesis/love interest for Adam Baldwin's Casey. Also confirmed to appear are LOST's Jeff Fahey, Smallville's Justin Hartley, Craig Kilborn and Community's Dani Pudi!