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admin | Matrix Exercise Equipment | 12.04.2015
Following initiation, as in conventional free-radical polymerization (i), the radical reversibly adds onto the chain transfer agent 1 to form an intermediate radical 2, which can fragment to liberate a reinitiating group and form a new dormant chain 3 (ii). Key Centre for Polymers & Colloids, School of Chemistry, the University of Sydney, Sydney, New South Wales 2006, Australia.
Religious carry candles in procession at the start of a Mass celebrated by Pope Francis to mark the feast of the Presentation of the Lord Feb. After growing up in Nigeria and being named the youngest bishop in the world at the age of 32, Cardinal Francis Arinze attended the final session of the Second Vatican Council.
Cardinal Arinze corresponded this past week with Catholic World Report about the meaning and uniqueness of consecrated life, the roots and development of consecrated life, and some of the challenges facing embracing and living the consecrated life today.
CWR: Along similar lines, how is consecrated life distinct from the lives of priests and bishops? Cardinal Arinze: The apostolate of priests and bishops is to celebrate the sacred mysteries, to preach the word of God, and to gather the people of God together in the parish and in the diocese.
Cardinal Arinze: The biblical roots of the consecrated life from the Old Testament are the lives of the prophets and the nazirites vowed to God (cf.
Cardinal Arinze: The origin of the three evangelical counsels is the life and example of Christ. CWR: The number of men and women in consecrated life apparently peaked, in the West, in the 1950s, and then dropped dramatically following the Council.
The laity can help, support and encourage their brothers and sisters living in the consecrated life in the following ways: prayer, advice, respect, working together at projects, encouraging their children or friends who are called to the consecrated life to embrace that vocation, and by donations in cash or kind. Activation of hydrocarbons over heterogeneous catalysts is a dynamic and growing field of research since the birth of the modern petroleum and natural gas industry. Besides the production of propylene, the activation of the C–H bond in methane is also an important but challenging process.
In the last few decades, density functional theory (DFT) has become a powerful tool for studying heterogeneous catalytic processes and their elementary steps and mechanisms at atomic scale.
This review describes mechanistic insights into heterogeneous catalytic dehydrogenation of light alkanes obtained from DFT calculations. For the investigation of solid states, DFT is an important and powerful method for quantum mechanical modeling developed in the last century. To describe a reaction, at least three data points need to be located on the potential energy surface: the initial, transition and final states. The energetics obtained directly from DFT calculations describe the potential energy surface at 0 K and 0 bar. Although the calculated reaction energies and barriers of the elementary steps provide useful clues to interpret the reaction mechanism, a more reliable method is to solve the steady-state at reaction conditions based on the calculated kinetic and thermodynamic information.
As the simplest hydrocarbon, activation of methane on transition-metal surfaces has been used numerous times as a model system since the early stage of theoretical calculations. Table 1 collected parts of previously calculated reaction energies and barriers of CH4 decomposition steps over close packed fcc(111)40–60 or hcp(0001)61 surfaces.
Table 1 List of calculated reaction and activation energies (kJ mol?1) for methane dehydrogenation on different metal surfaces.
At least two factors contribute to the relative high barriers of D4 among all four dehydrogenation steps, electronically and geometrically.
Table 1 also shows that, in general, CH4 decomposition barriers become higher along with the surface metal elements moving to the right of the periodic table. Following his elevation to cardinal by Pope John Paul II, he was appointed President of the Pontifical Council for Interreligious Dialogue, a position he held until 2002, when he became the first African Cardinal to head a Vatican office, the Congregation for Divine Worship and the Discipline of the Sacraments (2002-08). The layperson marries, looks for wealth, and conducts his or her own life and strives to do all this with the spirit of Christ.
Lives vowed to God in chastity, poverty and obedience are ways of following Christ with radical adherence to his Gospel message. In our weak human ways of explaining such developments we can say: In Europe and North America the number of men and women in the consecrated life went up in the 1950s because people had come out of the sufferings of the Second World War and learned that things of this world are passing away, there was relative stability in society and life in the Church and the family was reasonably stable.
How can the laity help support and encourage their brothers and sisters living the consecrated life?
Understanding the mechanism for the activation of C–H bonds in hydrocarbons provides fundamental insights into this process and a guideline for the optimization of catalysts used for the processing of light alkanes.
Recent development of hydraulic fracturing or “fracking” technologies have shown the ability to efficiently extract shale gas, which will increase the supply of CH4 as well as other light alkanes, mainly ethane and propane,1 rendering them a cheap and reliable source for chemical industry.2 On the other hand, light alkenes are important feedstocks for the production of polymers, oxygenates and many other important chemical intermediates. The relatively stable methane C–H ? bond, the negative electron affinity, the large ionization energy, the absence of a dipole moment and the extremely high pKa renders methane highly resistant to attacks by most redox active reagents, acids and bases. The progress of dehydrogenation using homogenous catalysts was recently reviewed by Balcells et al.10 and it will not be included in this review.
The terrace, edge and corner atoms on a metal particle can be approximately described by corresponding atoms on flat, step and kink surfaces, respectively. To describe a chemical process under realistic reaction conditions, thermodynamic corrections are necessary, which includes the zero point energy as well as the contributions to enthalpy and entropy at higher temperature and pressure. The most obverse signature for this series of reactions is the relatively high barriers for the first (D1) and last (D4) dehydrogenation steps, among many of which the barriers are higher than 100 kJ mol?1 (Table 1). The electronic effect is influenced by the relative stability of dehydrogenated intermediates.
Following the Nilsson and Pettersson model,62 the interaction between doubly occupied orbitals of adsorbates and high electron occupied d orbitals is repulsive. 8, 2012 I had a live blood microscopy with Rick Panson, a microbiologist, at the Live-Live store in NYC.
The rapid establishment of this reversible addition-fragmentation equilibrium (iv) allows for control over molecular weight and molecular-weight distribution, although irreversible termination reactions still occur, mainly due to the free radical introduced initially to initiate polymerization (v). Cardinal Arinze: The consecrated life is an embracing of the call to radical discipleship, the call to follow Christ in a radical way, because the consecrated person takes the vows of chastity, poverty and obedience.
It is to offer to God the sacrifice of the three best things on earth by the three evangelical counsels or vows of chastity, poverty and obedience. But more specifically it is the life and example of Jesus Christ in the New Testament that motivates the consecrated life. In the last two decades, density functional theory (DFT) has become a powerful tool to explore elementary steps and mechanisms of many heterogeneously catalyzed processes at the atomic scale. However, the undesired deep dehydrogenation leading to coke formation is also enhanced at high temperatures. Along with the development of novel computational architectures and the exponential increase in computational processor speed, the catalytic systems treated by DFT have developed from simple models such as metal or oxide single crystal surfaces to more sophisticated ones including alloys, supported catalysts and zeolites etc. We start with the background of density functional theory and its application for heterogonous catalysts.
However, the identification of a transition-state structure, which is a saddle point on the potential energy surface, is more challenging and computationally expensive. These corrections can be easily calculated according to statistical thermodynamics for an ideal gas. Although the steam reforming process is now widely used in the modern chemical industry, other alternative routes to process methane are still quite challenging.
In contrast, the barriers for D2 and D3 steps are mostly less than 80 kJ mol?1, and can be even as low as <10 kJ mol?1.


As we move to the right of periodic table from Ru, there are more electrons filled in the metal d band, and the repulsion between occupied orbital interactions becomes stronger. The life of Jesus was a model of the three virtues lived to an extraordinary degree of commitment. This review describes recent progress on computational understanding of heterogeneous catalytic dehydrogenation reactions of light alkanes. Thus, the development of strategies to avoid coke formation is an important field of research. It converts methane as well as other hydrocarbons into synthesis gas or hydrogen (with other byproducts), which can be further used in various processes to yield value added chemicals.
In addition, with advanced kinetic modeling, the rate constants of elementary steps calculated with DFT can be further converted to turnover rate under reaction conditions.
We then provide an overview addressing dehydrogenation reactions on metal or alloy surfaces, which represent the most studied area under this topic. However, the corrections for an adsorbed system, especially for the soft frustrated translation and rotation modes, are not always well defined. This leads to weak binding of surface intermediates, as well as poor stabilization of transition states. He spent an hour going over what he saw in my blood as well as giving me pointers that would move me into a greater state of health. All followers of Christ are indeed called to live three three virtues, but not in the same way. We start with a short description on basic concepts and principles of DFT as well as its application in heterogeneous catalysis. The robustness against coking can be increased with additional promoters, such as late transition metals, main-group metals including Sn and Ga, alkali-metal oxides and rare-earth metal oxides.6 However, the nature of atomic structure of these promoters during the dehydrogenation process is still under debate.
The reactions on three other types of catalysts, including oxides, zeolites and singe site (atom) catalysts are covered in the Section 4. However, for studies on heterogeneous catalysts, both PW91 and PBE functionals have several shortcomings, including over binding of surface intermediates17 and lack of van der Waals (vdW) dispersion interactions.18 The later developed revised PBE functional (RPBE17) improves the reproducibility of experimental binding energies for surface species. In the dimer method, the algorithm moves two images (dimer) uphill along the lowest curvature mode, which is estimated according to Voter's hyperdynamics method without evaluating the Hessian matrix, on the potential energy surface.28 Because of the complexity associated with the identification of a transition state, other attempts have been made to estimate the reaction barrier without explicitly obtaining the transition state structure and energy. Meanwhile, geometrically the perpendicular nature of CH is not favorable for further dehydrogenation, where an energy penalty needs to be applied to bend the structure parallel to surface in the transition state (Fig. Deeper dehydrogenation removes H atoms from the adsorbed intermediate, which results in more C–metal interaction, and eventually leads to higher reaction barriers. The activation of C–H bonds over transition metal and alloy surfaces are then discussed in detail, followed by C–H activation over oxides, zeolites and catalysts with single atoms as active sites. We then turn to the review of mechanistic studies on coke formation, which is one of the most common factors leading to catalyst deactivation during dehydrogenation reactions. Indeed, the total thermodynamics for CH4 = C* + 4H* is exothermic by 21 kJ mol?1 on Ru(0001), where Ru has 7 electrons in the d band.
It is one thing to have lab work and testing, and quite another to witness firsthand what is transpiring in your blood. The origins of coking formation are also discussed followed by a perspective on directions of future research.Zhi-Jian ZhaoZhi-Jian Zhao received his BS and MS degrees in chemistry from Zhejiang University and his PhD degree from Technische Universitat Munchen. As the reaction rates are essentially governed by only a few descriptors, a large number of potential catalysts can be screened rapidly by means of computational chemistry.8,9 Nevertheless, the fundamental understanding offered by DFT calculations still serves as a cornerstone in the complete process of computer-aided catalytic design (Fig. However, on Cu(111) where Cu has a filled d band, this process becomes strongly endothermic by 364 kJ mol?1, which is even much higher than highest kinetic barrier over Ru(0001). How do the consecrated life and the life of the lay person differ, and how do the two compliment and enrich one another? Jesus proposes: he does not impose the consecrated life as obligatory for any of his followers. In Africa, in particular, the success of missionary evangelization work and the dynamism shown by the young local churches have meant the growth of larger seminaries and the yearly increase of consecrated men and women. Similar strong bending of the adsorbate is also necessary for the D1 step, in order to move the C atom more close to the metal surface in the transition state. Also helpful is the general good health of the family in Africa, although generalizations should be avoided. Norskov and Dr Studt in Stanford University, he joined the faculty of Tianjin University in 2015. His current interest lies in molecular mechanistic understanding of heterogeneous catalytic reactions.Cheng-chau ChiuCheng-chau Chiu studied chemistry at the Technische Universitat Munchen, Germany, from which he obtained his BSc, MSc and PhD in 2008, 2010 and 2015, respectively.
At the bottom of the page are images that various people suffering with Morgellons graciously contributed to this site.A note on the photos. In his studies, he mainly examined the catalytic conversion of organic molecules over metal surfaces, but he has dealt with molecular processes in catalytic reactions catalyzed by zeolites or metal oxides.Jinlong GongJinlong Gong studied chemical engineering and received his BS and MS degrees from Tianjin University and his PhD degree from the University of Texas at Austin under the guidance of C. Rick provided me with photos for this page and I've filled in some of the gaps with screen grabs taken from the video that was taping our session.Nov. There are several stages of microorganisms? here which include yeast, bacteria and fibrin, fungus and mold. Whitesides as a postdoctoral fellow at Harvard University, he joined the faculty of Tianjin University, where he currently holds a Pei Yang Professorship in chemical engineering.
He has served on the editorial boards for several journals including Chemical Society Reviews and Chemical Science. In the background are 'shadow cells' which were healthy red blood cells that 'popped' due to the loss of their phospolipid membranes.
This can occur from an acid producing diet, and poor assimilation of nutrients.Rick's comments "Healthy blood cells will be perfectly round, nice and dark with a glowing halo around them.
Usually, if they have enough moisture inside them they are fully round because there is more pressure inside the cell then outside.""These 'shadow' or ghost cells were once perfectly healthy cells, you can see by their shape and color that they were—and they've now disappeared into the background. His research interests in surface science and catalysis include catalytic conversions of hydrocarbons and oxygenates, novel utilizations of carbon oxides, and synthesis and applications of nanostructured materials. Every cell in the body has a double membrane of fat made up of phospholipids, a two layer membrane.
The acids can disentegrate the cell membrane as well as when your body ferments sugar, alcohol is the byproduct, and alcohol can easily melt the cell membrane.""Whatever is happening in the blood cells is happening to the rest of the body.
Clotted mass of blood cells due to changes in the cells polarity, loss of natural negative electrical charge.
When there are this many cells and this little water, we are looking at the hydration level of the body.
These nets act as a defense mechanism for the bacteria so that the white blood cells can't get to them. There is no doubt that that is not part of normal healthy blood, and it's way bigger then what I think could survive in your cardiovascular system without being filtered out by your filter organs.
That's why I don't think it's a fiber, per se, because it's so big compared to everything else. From a biology point of view, my best guess is that it would be a contaminent that has nothing to do with you. The red blood cells are fermenting as the yeast eats the cell itself.Above: Neutrophils You go guys!


The other arrow is free-floating yeast, and you can see there is quite a bit of it in the blood. Sodium bicarbonate (baking soda) is the most important and most effective alkalizer your body makes to try and keep alkaline balance. This is not the greatest water filter but what it does is alkaline the water, so instead of drinking water that is pH 5 or 6, one is drinking water with a pH of 8-10 giving the body a running start on staying alkaline. The benefits of this water are it's antioxidant properties which nullify free radical scavengers, plus the extra oxygen in the water is supposed to give energy and boost alertness and memory.Candida detox Next on the plate is to tackle the candida with capyrilic acid and olive leaf extract (for about 2 months). I'm just going to take the recommended dosages on the bottles adding in one teaspoon of l-glutamine powder per day. The glutamine assists in strengthening the gut wall and helps patch any holes left by the yeast (which could lead to leaky gut syndrome and the problems it leads to, such as food allergies and parasites) Respiration "The biggest acid you make everyday is carbonic acid. Every cell in your body is producing carbon dioxide from the bottom of your feet to the top of your head that is also surrounded by water and the carbon dioxide plus water makes carbonic acid, that's a very simple thing to keep in mind. By looking for acid based balance the amount of acid produced per day must be equal to the amount excreted or nutralized per day. The thing that is happening is, if your body can't neutralize or eliminate the acid you stay at that level, you can't go beyond that level of health. You are taking the chest cavity, ribs and the lungs and trying to get them to be fantastic. Do 10 deep breaths a day 3x's a day (with long exhalation), in one month you are going to have a respiratory function that is 10%-15% better then you have now. Which means 10%-15% more energy and 10-15% less fermentation because fermentation only takes place where there is no oxygen.
It's the greatest tool you have and it's free."Alkalizing with baking soda "The methods of getting rid of acidity from the body are respiration, perspiration, defecation and urination. Rick gave me a great little tool (from the vet) that allows me to carry the soda in my back pocket making it more convienient to take. This is problematic for those of us taking supplements upon rising which are not supposed to be taken with clay. However, I'm trying to fit it in somewhere along the line.Magnesium oxide also called Oxy-Mag (NOW makes it). The process of oxygenating the bowel breaks down and eliminates solidified waste lodged in the large and small intestines. Beware, if you take it (up to one teaspoon at night in water with the juice of 1-2 lemons), you must leave time the next morning to eliminate fully. Rick says that eventually this watery stool will cease when the body is cleaned of accumulated waste. I try and do this once a week.Food During our session together I became increasingly confused about food. All those veggies will eventually turn to sugar so they have to be balanced out with oils and proteins. I was told by Nancy that each meal should have a carb, oil and protein and have been following that for some time.
Rick has said the same thing and suggested I start the day with a chia smoothie."The perfect breakfast would be 2 tablespoons of chia seeds, ground to be chia meal with 2 tablespoons of chlorophyl, (spirulina, chlorella or grass powders (greener grasses, alkavision greens). Ground flax seeds can be added." "Chlorophyll is very cleansing and is a blood builder and it has a molecular structure that looks almost identical to red blood cells. When you take the chia seed and the flax seeds which are 28% protein 40-50% omega 3 fatty acids, that's very little carbohydrate there.
The greens are 100% carbohydrate and when you mix them together, now you have carbs that burn like paper and you've got fats and oils, with proteins that don't really burn. The fats and oils are like the charcoal—now you have a sustained burn going on and then you don't ferment the sugars because the coal, the fatty acids, are there. So that breakfast with the chia seeds or flax seeds, or both, and any of those chlorophyls you are using can be a very beneficial superfood breakfast.
They time release and give it back to you so you have have nice long sustained energy with oils, proteins and carbs all day.
You'd be surprised, you don't need a lot of food, what you need is the right food."Rick suggested the more chia seeds used, the less hungry one will be. In fact, chia seeds have the highest known whole-food source levels of Omega-3 acids, as measured by percent of weight.• ?Rich In Antioxidants. Chia is a great natural source of antioxidants, including chlorogenic acid, caffeic acid, myricetin, quercetin and flavonols.• Full of Important Nutrients. Chia is an excellent source of calcium, phosphorus, magnesium, potassium, iron, zinc and copper. About five percent of this fiber is soluble, which can help reduce cholesterol.•  Builds Endurance. Chia builds stamina and endurance because it steadily releases slow-burning glucose into the bloodstream.• ?Gluten-Free.
Since essential amino acids are not produced by the body, it's important to get amino acids from nutrient-rich sources like chia seeds.
Research suggests leucine may help regulate blood sugar levels and aid in muscle recovery after exercise.• ?Stays Fresh.
16, 2012 • 2nd Live blood microscopyI saw Rick for a second live blood analysis on November 16, 2012. No ghost cells, no rouleax or sticky blood, the red blood cells are fuller, look stronger and are hydrated. Candida has been greatly reduced in just 2+ months.?The treatment of olive leaf extract, caprylic acid and l-glutamine powder as per his suggestion for candida is working. I began addressing it by taking one capsule of both the olive leaf and caprylic acid plus one heaping tsp.
After I was sure I had no reactions to this, upped the dosage to 2 caps of each with one tsp. That is not to say that the Morgellons has been effected, we saw two fibers in the dried blood samples.
There seemed to me to be more bacteria in the blood and the white blood cells although they are strong and were very active were not plentiful. I attribute the lower level of white blood cell activity to the fact that I was more sedentary these past two months then normally due to a foot problem that kept me off it. Rick suggested that I do lymphatic drainage work using a brush or mitt, followed by getting on a rebounder to jumpstart the lymph moving. He feels that getting the lymphatics going will produce more white blood cells to remove the bacteria from the blood.The chia seeds in the morning are wonderful. Rick suggests way to activate more white blood cell activity by way of the lymphatic system.



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